1-Phenyl-2-Nitropropene (P2NP)


1-Phenyl-2-Nitropropene (P2NP) is a representative of fatty aromatic unsaturated nitro compounds. Externally, it is a yellow needle-shaped crystals with a peculiar smell. It irritates the mucous membranes, leaves difficult-to-heal ulcers on the skin. Phenylnitropropene is highly CH-acidic.

IUPAC name: 1-Phenyl-2-nitropropene, 1-Phenyl-2-nitropropene

Common names: 1 Phenyl 2 Nitropropene, 1-Phenyl-2-nitropropene, P2NP, P2NP, Phenylnitropropene, (2-nitropropen-1-yl), (2-Nitropropenyl) benzene, Phenyl-2-nitropropene, Wikipedol, nikropropene, Phenyl-2-nitropropene, Phenyl-2-nitropropene, Phenyl-2-nitropropene, (2-Nitropropenyl) benzene, Phenyl-2-nitropropene

Molecular formula: C9H9NO2
Molar mass: 163.17 g mol-1
Appearance: yellow needles
Melting point: 64-66 ° C

Solubility: insoluble in water, soluble in organic solvents (ethanol, glacial acetic acid, acetonitrile, isopropanol, tetrahydrofuran (THF), diethyl ether)

1-Phenyl-2-nitropropene (phenyl-2-nitropropene, phenylnitropropene) has found application in fine organic synthesis, in particular the synthesis of phenyl-2-propanol, phenyl-2-propanol oxime, phenyl-2-nitropropane, and others. Can also be used in the manufacture of pharmaceuticals.

Nitropropene (chemical reference)
Somewhat later, by the step hydrogenation of furylnitroethylene was reduced to 1-furyl-2-aminoethane. According to patent data, 1-phenyl-2-nitropropen-1 by treatment with sodium amalgam in an alcohol-acetic acid medium was immediately converted into 1-phenyl-2-aminopropane, isolated as a salt.

The addition of acetylene to nitromethane leads to 1-nitropropene. In this case, the primary condensation product is considered to be 3-nitropropene, which then undergoes a rearrangement, moving the double bond to a position that ensures its conjugation with the nitro group.

Nitro-olefins, in turn, can undergo various transformations, for example, they can be reduced to the corresponding 1-phenyl-2-nitropropen-1 amines by hydrogenation in the presence of a Raney nickel catalyst, yielding the corresponding amine in 40% yield [61] From y-nitrostyrene by hydrogenation in the presence of platinum oxide, p-phenethylamine can be obtained in 93% yield, and 3,4-methylenedioxy-nitrostyrene and 3-nitrosy nitrostyrene in the presence of the same catalyst are hydrogenated to the corresponding amine 17.

Nitropropene (formula)


Additional information


0.5 kg, 1 kg, 5 kg, 10 Kg


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